Kodak Module 9 specifications Bleach Persulfate Bleach, Accelerator AB-1b AB-1bR

Accelerator

Constituent	Fresh Tank	Fresh and Seasoned Tank	Fresh	Replenisher Analytical
		Analytical Specifications	Replenisher	Specifications
Accelerator *	(AB-1b)		(AB-1bR)
Water 24- 38°C (75-100°F)	900 mL		900 mL
Sodium Metabisulfite (Anhydrous)	3.3 g	2.0 ± 0.5 g/L†	5.6 g	3.3 ± 0.5 g/L†
Acetic Acid (Glacial)	5.0 mL	5.0 ± 0.5 mL/L‡	7.0 mL/L	7.0 ± 0.5 m/L‡
Persulfate Bleach Accelerator PBA-1	3.3 g	3.3 ± 0.3 g/L	4.9 g	4.9 ± 0.3 g/L
or	or	or	or	or
KODAK liquid PBA-1§	4.0 mL	4.0 ± 0.4 mL/L	5.9 mL	5.9 ± 0.4 mL/L
(Ethylenedinitrilo)	0.5 g		0.7 g
Tetraacetic Acid Tetrasodium Salt
Water to make	1 L		1 L
pH at 25.0°C (77.0°F)		4.0 ± 0.2		3. ± 0.2
Specific Gravity at 25.0°C (77.0°F)		1.007 ± 0.003		1.012 ± 0.003
		1.031 ± 0.003
		(seasoned)

*Mixing the accelerator with high agitation for extended periods of time results in loss of some PBA-1 due to aerial oxidation. Mix the accelerator only

until all chemicals are dissolved.

†The analytical method measures the total sulfite content of the solution and reports it as sodium metabisulfite (Na 2S2O5). If a solution addition to the sodium metabisulfite level must be made but sodium bisulfite is to be used, multiply the sodium metabisulfite addition weight by the factor 1.09 to obtain the equivalent amount of sodium bisulfite.

The difference between mix level and the analytical specification occurs because some sulfite is consumed in a reaction with KODAK Persulfate Bleach Accelerator PBA-1 to form the active accelerator species “in situ.”

‡ The analytical method measures buffer capacity and results are reported in terms of glacial acetic acid. Adjustment in pH sho uld be made with glacial acetic acid or 50% sodium hydroxide.

§For convenience, add PBA-1 from a 250 g/L stock solution. Prepare by dissolving 5 kg PBA-1 in water and diluting to 20 L. Each 4 mL of stock solution contains 1 g PBA-1. For a 100 L replenisher of AB-1bR, add 1.96 L of stock solution.

To process VISION Premier Color Print Film, the accelerator replenisher flow rate may need to be increased. If only a small amount of footage is processed no change in the flow rate should be required in the replenisher. For larger quantities of VISION Premier Color Print Film (more than one tank turnover), it is recommended to increase the flow rate by approximately 20% and closely monitor the PBA-1 level and retained silver in the D-max area of the film.

Bleach

Persulfate Bleach

Only to be used in combination with accelerator solution.

Constituent	Fresh Tank	Fresh and Seasoned Tank	Fresh	Replenisher Analytical
		Analytical Specifications	Replenisher	Specifications
Persulfate Bleach	(SR-30)		(SR-30R)
Water 24-38°C (75-100°F)	850 mL		800 mL
Chlorine Scavenger *	0.35 g		0.50 g
Sodium Persulfate	33 g	30 ± 2 g/L	52 g	48 ± 3 g/L
Sodium Chloride	15 g	15 ± 3 g/L	20 g	20 ± 2 g/L
Sodium Dihydrogen Phosphate	7.0 g		10.0 g
(Anhydrous)
Phosphoric Acid (85%)	2.5 mL	7.0 ± 1.0 mL/L†	2.5 mL	8.8 ± 1.0 mL/L†
Water to make	1 L		1 L
pH at 25.0°C (77.0°F)		2.3 ± 0.2		2.4 ± 0.2
Specific Gravity at 25.0°C (77.0°F)		1.037 ± 0.003 (fresh)		1.059 ± 0.003
		1.085 (seasoned)‡

*Since there are many acceptable chlorine scavengers, convenience of use and cost may be factors in making a choice. Hydrolysate, a soluble version of gelatin, is available from U.S. Gelatin Corporation. Both food and photographic-grade gelatin have been used successfully. The gelatin must first

be dissolved in 40°C (104°F) water and stirred for 20 minutes. Up to 50 g/L can be added in this way in order to make a stock solution for subsequent use. Beta-aminopropionic acid is higher cost alternative offering easy solubility.

†The analytical method measures the buffer capacity of the bleach and reports the result as mL/L of phosphoric acid (85%). The analytical specification (7.0 mL) is larger than the amount of phosphoric acid added (2.5 mL) because dihydrogen phosphate (and sulfate in seasoned solutions) also contributes to the measurement. If a correction must be made, phosphoric acid (85%) can be added on a mL-for-mL basis. For example, if the tank analysis reports 5.0 mL/L, then the correction would be to add 2.0 mL/L of phosphoric acid (85%).

‡If the bleach tank overflow is being reused, the specific gravity (a measure of sulfate ion buildup) should not exceed this v alue as incomplete bleaching could occur.

9-22 Process ECP-2E Specifications