Primary Lithium Batteries

Manganese Dioxide Primary Lithium Batteries (CR

Sanyo manganese dioxide primary lithium batteries, developed in 1976, feature high energy density. Because they offer many unique features not found in either convetional dry cells or silver oxide batteries, Sanyo lithium batteries are currently used in a wide range of equipment such as electronic calculators, watches and cameras. In addition, they are used as a memory backup power source in microcomputer-controlled devices. By offering a wide range of lithium batteries, from coin cells to high-power cylindrical type cells (spiral structure) and high-capacity cylindrical type cells (bobbin structure), Sanyo has been able to meet the demands of a large and diversified market.

Sanyo is acquiring International Regulation ISO9001 approval which is a quality guarantee. Sanyo continues to implement thorough quality control.

Principles and Structure of Primary Lithium Batteries

Applying an original manufacturing process, Sanyo uses a manganese dioxide compound as the active material for the positive electrode (cathode). Lithium is used for the negative electrode (anode) to produce a cell with high voltage and high energy density. In addition, an organic electrolyte is employed to which lithium salts are added.

The discharge reaction of lithium batteries is as follows:

Anode reaction: LiLie

Cathode reaction: MnO2LieMnO2 (Li)

Overall battery reaction: MnO2LiMnO2 (Li)

The cell voltage is approximately 3V.

Battery Structure

High-power cylindrical type lithium batteries are capable of producing a very high discharge current due to their spiral electrode structure. High-capacity cylindrical type lithium batteries have a bobbin structure which contains active material and can provide a high capacity.

In addition, the laser sealing technology ensures long-term reliability and a battery life of up to 10 years at room temperature.

Coin Type Primary Lithium Batteries (crimp-sealing)

negative cap

anode (lithium)

 

separatorelectrolyte

 

gasket

 

cathode (MnO2)

 

positive can

Cylindrical Type Primary Lithium Batteries

High-power (spiral structure)

 

High-capacity (bobbin structure)

Crimp-sealing

 

Laser-sealing

 

 

Laser-sealing

positive cap with safety vent

PTC device

negative cap

gasket

negative cap

gasket

laser-sealed section

 

laser-sealed section

 

 

 

 

 

 

 

 

 

gasket

 

 

 

 

 

 

 

positive tab

 

negative current collector

 

 

 

 

 

 

positive tab

 

negative tab

 

 

 

anode (lithium)

 

 

 

 

 

 

 

 

 

cathode (MnO2)

separatorelectrolyte

 

cathode (MnO2)

 

 

 

 

 

separatorelectrolyte

 

 

separatorelectrolyte

 

 

cathode (MnO2)

 

 

 

 

 

 

 

 

 

 

anode (lithium)

 

anode (lithium)

 

 

 

 

 

 

insulator plate

 

 

 

 

 

 

 

insulator sheet

 

positive can

 

 

 

 

 

negative tab

negative can

positive can with safety

 

 

 

 

 

 

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