(OPTICAL) port on your TV and the Digital Audio Input on the Home Theater.

–– To hear 5.1 channel audio, connect HDMI cables to your Anynet+ DVD player, satellite box, etc. Then, connect the DIGITAL AUDIO OUT (OPTICAL) port on your DVD player, Satellite Box, etc. (i.e. Anynet + Device 1 or 2) directly to the Home Theater, not the TV.

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Samsung PN64E8000 manual