We recommend to use Intel® Z77 SATA ports (SATA3_0, SATA3_1, SATA2_2, SATA2_3, SATA2_4 and SATA2_5) for your bootable devices. This will minimum your boot time and get the best performance. But if you still want to boot from ASMedia SATA3 controller, you can still enable this in UEFI.

3.4.5 Intel(R) Rapid Start Technology

Intel(R) Rapid Start Technology

Use this item to enable or disable Intel(R) Rapid Start Technology. Intel(R) Rapid Start Technology is a new zero power hibernation mode which al- lows users to resume in just 5-6 seconds. The default is [Disabled].

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ASRock Fatal1ty Z77 Professional-M manual IntelR Rapid Start Technology