Salt water contains four kinds of ions; sodium ions (Na+), chlorine ions
NaCl + H2O | → | Na+ + Cl- + H+ + OH- |
(Mix water and salt) |
| Salt water (4 kinds of ions) |
When two electrodes are inserted into salt water and voltage is applied:
Negative ions
Positive ions (Na+) are drawn to the cathode.
At the anode, hydrogen chloride (HCl) and hypochlorous acid (HOCl) are generated.
2Cl- + H2O → HCl + HOCl + 2e-
Electrons
oxidization. [As electrons are emitted, the oxidization/reduction potential becomes positive (+mV).]
Chlorine ions also emit electrons and become chlorine gas (Cl2).
2Cl- → | Cl2 + 2e- |
| (Cl2 = chlorine gas) |
At the cathode, sodium hydroxide (NaOH) and hydrogen gas (H2) are generated.
Na+ + H2O + H+ + 2e- → NaOH + H2
Electrons
13