Duracell Ni-MH manual Basic Cell Construction, Cylindrical Cell Construction

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Ni-MH Rechargeable Batteries

4Battery Construction

DURACELL standard-sized nickel-metal hydride batteries are constructed with cylindrical and prismatic nickel- metal hydride cells. DURACELL nickel-metal hydride batteries are a sealed construction designed for optimal perfor- mance and maximum safety. The batteries are manufactured to strict quality control standards to ensure reliability and consumer satisfaction and offer such features as:

High energy density — Minimizes battery volume and weight

Wide voltage range — Meets operating voltage requirements of 3C devices

Thin profiles — Innovative wall-less design

Advanced interconnect — Self securing, voltage- keyed interconnect provides a highly reliable battery- to-device contact

Durability — Manufactured with LEXAN® and LUSTRAN® polycarbonate high impact and flame retardant polymers

UL listing — Independent approval of battery use in devices

LEXAN® is a registered trademark of the General Electric Company.

LUSTRAN® is a registered trademark of the Monsanto Company.

4.1 Basic Cell Construction

The electrodes in both cylindrical and prismatic cell configurations are designed with highly porous structures which have large surface areas to provide low internal resistance which results in superior high rate performance. The positive electrode in the cylindrical

nickel-metal hydride cell is a highly porous nickel-felt substrate into which the nickel compounds are pasted. Similarly, the negative electrode is a perforated nickel- plated steel foil onto which the plastic-bonded, active hydrogen storage alloy is coated.

4.2 Cylindrical Cell Construction

The assembly of a cylindrical cell is shown in Figure 4.2.1. The electrodes are separated by the sepa- rator which is a synthetic, non-woven material that serves as an insulator between the two electrodes and as a medium for absorbing the electrolyte. The electrodes are spirally-woundand inserted into a cylindrical nickel- plated steel can. The electrolyte is added and contained within the pores of the electrodes and separator.

The positive electrode is connected to the metal lid with a tab. The cell is then sealed by crimping the

top assembly to the can. The top assembly incorporates a resealable safety vent, a metal lid and a plastic gasket. A heat-shrink tube is placed over the metal can. The bottom of the metal can serves as the negative terminal and the metal lid as the positive terminal. The insulator and gasket insulate the terminals from each other. The vent provides additional safety by releasing any excess pressure that may build up if the battery is subjected to abusive conditions.

FIGURE 4.2.1

Metal Can

 

Separator

 

 

 

 

 

Negative Electrode

 

 

 

Heat Shrink Tube

 

 

 

Positive Electrode

 

 

 

(-) Negative Terminal

 

 

 

Insulator

 

 

 

Positive Tab

 

 

 

 

 

 

Metal Lid

 

 

 

Safety Vent

 

 

Cosmetic Disk

(+) Positive Terminal

 

 

Gasket

4

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Contents Ni-MH Rechargeable Batteries Able of ContentsNi-MH Rechargeable Batteries 1 Introduction Cell Reactions Active Components Positive and Negative ElectrodesElectrolyte Composition and Chemistry Cylindrical Cell Construction Basic Cell ConstructionPrismatic Cell Construction Battery ConstructionGeneral Characteristics Performance CharacteristicsEnergy Density Pe rformance CharacteristicsCapacity Effect of Discharge Rate and Temperature Polarity Reversal During Overdischarge Constant Power Discharge CharacteristicsPerf ormance Char acteristics Self-Discharge and Charge Retention Performance Ch aracteristicsInternal Impedance Voltage Depression Memory Effect Performance Cha racteristicsGeneral Principles Charging Sealed Nickel-Metal Hydride BatteriesTechniques for Charge Control Charging Sealed Nickel-Metal Hydride Batt eriesCharging Sealed Nickel-Metal Hydride Batt eries co nt Temperature CutoffTimed Charge Voltage Plateau Zero ΔVCharging Methods Delta Temperature Cutoff ΔtcoRate of Temperature Increase dT/dt Low-Rate Charge ≈12 hours Duracell’s Recommendation Three-Step Charge ProcedureQuick Charge ≈4 hours Fast Charge ≈1 hourTrickle Charge Thermal DevicesCycle Life Cycle and Battery LifeRecommended Permissible Battery LifeSafety Considerations Test Test Conditions Test Results Care and Handling Transportation Proper Use and Handling