Duracell Ni-MH manual Performance Characteristics, General Characteristics

Page 7

Ni-MH Rechargeable Batteries

5PerformanceCharacteristics

5.1 General Characteristics

The discharge characteristics of the nickel-metal hydride cell are very similar to those of the nickel- cadmium cell. The charged open circuit voltage of both systems ranges from 1.25 to 1.35 volts per cell. On discharge, the nominal voltage is 1.2 volts per cell and the typical end voltage is 1.0 volt per cell.

Figure 5.1.1 illustrates the discharge character- istics of nickel-metal hydride and nickel-cadmium rechargeable cells of the same size. As shown, the volt- age profile of both types of cells is flat throughout most of the discharge. The midpoint voltage can range from

1.25to 1.1 volts per cell, depending on the discharge load. Figure 5.1.1 can also be used to compare the capacity of the two rechargeable types. Note that the capacity of the nickel-metal hydride cell is typically up to 40 percent higher than that of a nickel-cadmium cell of equivalent size.

FIGURE 5.1.1

 

1.5

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

1.4

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

(V)

1.3

 

 

 

 

 

 

 

 

 

 

1.2

 

 

 

 

 

 

 

 

 

 

Voltage

 

 

 

 

 

 

 

 

C/5

 

1.1

 

 

 

 

 

C/5

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

1.0

 

 

 

 

 

 

Ni-Cd

 

Ni-MH

 

.9

 

 

 

 

 

 

 

 

0

20

40

60

80

100

120

140

160

Ampere-Hour Capacity (%)

Comparison of discharge voltage and capacity of same-size Ni-MH and Ni-Cd cells.

[Conditions: Charge: C/3 for 5 hours, Temperature: 21°C (70°F)]

5.2Discharge Characteristics: Effect of Discharge Rate and Temperature

Typical discharge curves for DURACELL nickel- metal hydride batteries under constant current loads at various temperatures are shown in Figures 5.2.1 to

5.2.3.Discharge voltage is dependent on discharge

current and discharge temperature.

FIGURE 5.2.1

 

8.5

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

8.0

 

 

 

 

 

Temperature:

45°C (113°F)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

7.5

 

 

 

 

 

 

 

 

 

 

 

 

 

(V)

 

 

 

 

C (2.4A)

 

 

C/5 (0.48A)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Voltage

 

 

 

 

 

 

 

 

 

 

 

 

 

7.0

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

6.5

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

6.0

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

5.5 0

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

0.5

1.0

1.5

2.0

 

 

2.5

 

 

 

 

Discharge Capacity (Ah)

 

 

 

 

 

 

 

FIGURE 5.2.2

 

8.5

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Temperature:

21°C (70°F)

 

 

8.0

 

 

 

 

 

 

 

 

 

 

 

 

 

 

7.5

 

 

 

 

 

 

(V)

 

 

C (2.4A)

 

C/5 (0.48A)

 

 

 

 

 

 

 

 

 

 

Voltage

7.0

 

 

 

 

 

 

 

 

 

 

 

 

 

 

6.5

 

 

 

 

 

 

 

 

 

 

 

 

 

 

6.0

 

 

 

 

 

 

 

 

 

 

 

 

 

 

5.5

 

 

 

 

 

 

 

 

 

 

 

 

 

0

0.5

1.0

1.5

2.0

2.5

 

 

Discharge Capacity (Ah)

 

 

FIGURE 5.2.3

 

8.5

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Temperature:

-20°C (-4°F)

 

 

 

 

 

8.0

 

 

 

 

 

Temperature:

 

0°C (32°F)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

C/5 (0.48A)

 

 

 

 

 

 

 

 

 

7.5

 

 

 

 

 

 

 

 

 

 

(V)

 

 

 

 

C/5 (0.48A)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Voltage

7.0

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

C (2.4A)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

6.5

 

 

 

 

C (2.4A)

 

 

 

 

 

 

 

 

 

 

C (2.4A)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

6.0

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

5.5

 

 

 

 

 

 

 

 

 

 

 

 

 

 

0.5

1.0

1.5

2.0

2.5

 

0

Discharge Capacity (Ah)

Voltage and capacity of DURACELL DR30 Ni-MH batteries at various discharge temperatures and rates.

[Conditions: Charge: 1C to -ΔV = 60mV @ 21°C (70°F)]

6

Image 7
Contents Ni-MH Rechargeable Batteries Able of ContentsNi-MH Rechargeable Batteries 1 Introduction Electrolyte Active Components Positive and Negative ElectrodesCell Reactions Composition and Chemistry Cylindrical Cell Construction Basic Cell ConstructionPrismatic Cell Construction Battery ConstructionGeneral Characteristics Performance CharacteristicsCapacity Effect of Discharge Rate and Temperature Pe rformance CharacteristicsEnergy Density Perf ormance Char acteristics Constant Power Discharge CharacteristicsPolarity Reversal During Overdischarge Internal Impedance Performance Ch aracteristicsSelf-Discharge and Charge Retention Voltage Depression Memory Effect Performance Cha racteristicsGeneral Principles Charging Sealed Nickel-Metal Hydride BatteriesTechniques for Charge Control Charging Sealed Nickel-Metal Hydride Batt eriesVoltage Plateau Zero ΔV Temperature CutoffCharging Sealed Nickel-Metal Hydride Batt eries co nt Timed ChargeRate of Temperature Increase dT/dt Delta Temperature Cutoff ΔtcoCharging Methods Fast Charge ≈1 hour Duracell’s Recommendation Three-Step Charge ProcedureLow-Rate Charge ≈12 hours Quick Charge ≈4 hoursTrickle Charge Thermal DevicesCycle Life Cycle and Battery LifeRecommended Permissible Battery LifeSafety Considerations Test Test Conditions Test Results Care and Handling Transportation Proper Use and Handling