Example Potentiometric Calculations:

Titration

 

mL 0.1 N Na2S2O3 Titrant

Blank A

=

40.50

Sample A

=

21.85

Blank B

=

40.55

Sample B

=

19.80

Hypo Index (HI) or Total Reductants:

(40.50 – 21.85)(0.0989)

HI (1), mL =

0.1000

= 18.4 mL 0.1000 N I2

Thiosulfate (S2O3=):

g/L S2O3= =

(40.55 – 19.80)(0.0989)(112.13)(1000)

(2.0)(1000)

= 57.5 g/L

Sodium Sulfite (Na2SO3):

[(40.50 – 21.85)(2.0) – (40.55 – 19.80)](0.0989)(63.02)(1000)

g/L Na2SO3 =

(2.0)(1000)

= 51.4 g/L

Processing KODAK Motion Picture Films, Module 3, Analytical Procedures • H24.03

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Kodak ECN-0002/1 manual Example Potentiometric Calculations