Teledyne 3000TA operating instructions Effect of Pressure, Calibration Characteristics

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Operational Theory

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measured and used to determine the oxygen concentration in the gas mixture.

The overall reaction for the fuel cell is the SUM of the half reactions above, or:

2Pb + O2→2PbO

(These reactions will hold as long as no gaseous components capable of oxidizing lead—such as iodine, bromine, chlorine and fluorine—are present in the sample.)

The output of the fuel cell is limited by (1) the amount of oxygen in the cell at the time and (2) the amount of stored anode material.

In the absence of oxygen, no current is generated.

2.2.4 The Effect of Pressure

In order to state the amount of oxygen present in the sample in parts-per-million or a percentage of the gas mixture, it is necessary that the sample diffuse into the cell under constant pressure.

If the total pressure increases, the rate that oxygen reaches the cathode through the diffusing membrane will also increase. The electron transfer, and therefore the external current, will increase, even though the oxygen concentration of the sample has not changed. It is therefore important that the sample pressure at the fuel cell (usually vent pressure) remain relatively constant between calibrations.

2.2.5 Calibration Characteristics

Given that the total pressure of the sample gas on the surface of the Micro-Fuel Cell input is constant, a convenient characteristic of the cell is that the current produced in an external circuit is directly proportional to the rate at which oxygen molecules reach the cathode, and this rate is directly proportional to the concentration of oxygen in the gaseous mix- ture. In other words it has a linear characteristic curve, as shown in Figure 2-3. Measuring circuits do not have to compensate for nonlinearities.

In addition, since there is zero output in the absence oxygen, the characteristic curve has close to an absolute zero (within ± 1 ppm oxygen). In practical application, zeroing may still used to compensate for the combined zero offsets of the cell and the electronics. (The

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Contents Model 3000TA Teledyne Analytical Instruments3000TA- EU Copyright 2011 Teledyne Analytical InstrumentsSpecific Model Information Trace Oxygen AnalyzerImportant Notice Safety Messages 3000TA- EU Vii Table of Contents Maintenance OperationAppendix List of Figures Model 3000TA Front PanelList of Tables Overview Main Features of the AnalyzerIntroduction Typical ApplicationsModel Designations Introduction 3000TA- EUFront Panel Operator Interface Model 3000TA Front PanelRecognizing Difference Between LCD & VFD Rear Panel Equipment Interface ∙ 50-Pin Equipment Interface PortIntroduction 3000TA- EU Micro-Fuel Cell Sensor Operational TheoryIntroduction Trace Oxygen Analyzer Operational TheoryOperational Theory 3000TA- EU Anatomy of a Micro-Fuel CellElectrochemical Reactions Calibration Characteristics Effect of PressureCharacteristic Input/Output Curve for a Micro-Fuel Cell Sample SystemPiping Layout and Flow Diagram for Standard Model Electronics and Signal Processing Flow Diagram3000TA Internal Electronic Component Location Block Diagram of the Model 3000TA-EU Electronics Operational Theory 3000TA- EU Unpacking the Analyzer InstallationTrace Oxygen Analyzer Installation Mounting the AnalyzerInstallation 3000TA- EU Front Panel of the Model 3000TARear Panel Connections Gas ConnectionsSample Exhaust OUT Electrical ConnectionsEquipment Interface Connector Pin Arrangement ∙ Threshold Alarm Alarm Relay Contact Pins Pin Function Range ID Relay Connections Remote Probe Connections 2.3 RS-232 PortCommands via RS-232 Input Installing the Micro-Fuel Cell Testing the SystemPage Operation Using the Data Entry and Function ButtonsTrace Oxygen Analyzer Operation Operation 3000TA- EU System Function Hierarchy of Functions and Sub functionsTracking Oxygen Readings During Calibration and Alarm Delay TRAK/HLD Auto-Cal Pswd Logout More Setting up an Auto-Cal Password Protection A a a Characters Available for Password Definition Logout System Self-Diagnostic Test Version Screen Showing Negative Oxygen ReadingsZero and Span Functions Zero Cal Zero Settling Man ENT To Begin Span Cal Span Val 000008.00 ENTSpan UPMod # #### % Span Slope=#### ppm/s Alarms Function Span FailureAL-1AL-2 Choose Alarm Range Function Setting the Analog Output Ranges Fixed Range Analysis Signal Output Analyze FunctionMED Operation 3000TA- EU Teledyne Analytical Instruments Trace Oxygen Analyzer Maintenance MaintenanceRoutine Maintenance Storing and Handling Replacement CellsWhen to Replace a Cell Maintenance 3000TA- EURemoving the Micro-Fuel Cell Installing a New Micro-Fuel Cell Removing the Micro-FuelMaintenance 3000TA- EU Fuse Replacement Cell WarrantySystem Self Diagnostic Test Installing FusesMajor Internal Components Cleaning TroubleshootingTrace Oxygen Analyzer Maintenance Maintenance 3000TA- EU Teledyne Analytical Instruments Appendix Model 3000TA SpecificationsTrace Oxygen Analyzer Appendix Recommended 2-Year Spare Parts List Appendix 3000TA- EUOrders should be sent to Drawing List 19-inch Relay Rack Panel MountApplication notes Flow Rate Recommendations3000TA Examples Bypass Conversions Section I Product Identification Material Safety Data SheetSection II Physical and Chemical Data Appendix 3000TA- EU Section III -Physical Hazards Section IV Health Hazard DataSection VI Handling Information
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3000TA specifications

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