UL Bleach Formulations

Two UL Bleach formulations are available to fill various laboratory operating and environmental needs. They are:

Ammonium UL or “UL House” Bleach. This formulation contains the highest percentage of ammonium ion which maximizes bleach activity. Because the least amount of active ingredients are necessary, this is the least expensive of the UL bleach varieties to operate. The use of ammonia in a laboratory may present some handling and odor considerations and is restricted in some sewer districts.

The “UL House” Bleach formulation was derived to allow for a common tank and replenisher to be used for both Processes ECN and ECP. Its advantage is less mixing and solution handling between the two processes.

Potassium “UL House” Bleach combines the advantages of a non-ammonium formulation with a house system where one replenisher feeds tanks for both Processes ECN and ECP. Through replenisher rate manipulation, the tanks for Processes ECN and ECP are maintained at appropriate levels so bleaching is completed while excess carryout is avoided.

Selecting a Bleach Formulation

Experimentation has shown that an all-ammonium bleach is the most active and, therefore, needs the minimum amount of iron (and the associated amount of PDTA) for adequate bleaching. When potassium cations are substituted for ammonium, more iron is needed to complete bleaching for the same time and temperature. The best formulation for use in a given lab should be determined based on several operating factors. Some of the factors to consider are:

Local chemical cost and availability

Laboratory ventilation factors

Restrictions on sewer discharge

Controlling Bleach Tank Concentration with Replenisher Rate

Since bleach systems are subject to evaporation in the machine, overflow and replenisher holding tanks, system evaporation often plays a significant part in striking a balance between replenisher concentration, replenisher rate, and tank concentration. The best way to adjust between these factors, especially in a house system, is to vary the replenisher rate to maintain the desired tank concentration. Allowing the tank concentration to run high creates waste due to carryout. A low tank concentration presents the danger of inadequate bleaching. A new system should be started up using the suggested replenisher rates given for each bleach version. As the process or system seasons, the rates may be adjusted to give the desired tank concentrations. Bromide, iron, and pH are the critical parameters and should stay within limits given. If bromide or iron is too high, no harm to the process or film will occur, but expensive chemicals will be wasted due to carryout.

Conversion to UL Bleach

The advantages of converting to the UL bleach, from ferricyanide bleach (SR-27) are:

UL bleach maintains a cleaner tank

UL bleach forms no prussian blue

UL bleach is easier to regenerate

UL bleach regenerates into a cleaner replenisher

The advantages of converting to the UL bleach, from persulfate bleach are:

UL bleach has more bleaching power

UL bleach has a longer solution life

UL bleach is less sensitive to process variations

Mechanical changes are minor; adjust controls to keep the bleach at 27°C (80°F). Solution times and replenishment rates do not change.

If using the ferricyanide bleach currently, first remove any red brass from the system, then clean up the bleach system. A high pH wash (10 to 12) will help eliminate any prussian blue in the system. Three cleaning cycles are recommended.

If persulfate bleach is now in your machine, a series of hot water rinses is needed in the accelerator and bleach tanks. The bleach and accelerator tanks should be filled with hot water and the recirculation and replenishment system turned on. Three to five cleaning cycles are recommended.

Process ECP-2E Specifications

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Kodak Module 9 specifications UL Bleach Formulations, Conversion to UL Bleach, Selecting a Bleach Formulation

Module 9 specifications

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