MODEL 54eA
16.15 MEASURING REFERENCE VOLTAGE
Some processes contain substances that poison or shift the potential of the reference electrode. Sulfide is a good example. Prolonged exposure to sulfide converts the ref- erence electrode from a silver/silver chloride electrode to a silver/silver sulfide electrode. The change in reference voltage is several hundred millivolts. A good way to check for poisoning is to compare the voltage of the reference electrode with a silver/silver chloride electrode known to be good. The reference electrode from a new sensor is best. See Figure
SECTION 16.0
TROUBLESHOOTING
FIGURE 16-6. Checking for a Poisoned
Reference Electrode.
Refer to the sensor wiring diagram to identify the reference leads. A laboratory silver/silver chloride electrode can be used in place of the second sensor.