Emerson Process Management 53eA Sensor does not respond to changes in ozone level

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MODEL 54eA

SECTION 16.0

 

TROUBLESHOOTING

16.8.4 Process readings are erratic

A.Readings are often erratic when a new sensor or a rebuilt sensor is first placed in service. The current usual- ly stabilizes after a few hours.

B.Is the sample flow within the recommended range? High sample flow may cause erratic readings. Refer to the sensor instruction sheet for recommended flow rates.

C.Are the holes between the membrane and the electrolyte reservoir open. Refer to Section 16.8.2.

D.Verify that wiring is correct. Pay particular attention to shield and ground connections.

E.Is the membrane in good condition and is the sensor filled with electrolyte solution? Replace the fill solution and electrolyte. Refer to the sensor instruction manual for details.

15.8.5 Readings drift

A.Is the sample temperature changing? Membrane permeability is a function of temperature. The time constant for the 499AOZ sensor is about five minutes. Therefore, the reading may drift for a while after a sudden tem- perature change.

B.Is the membrane clean? For the sensor to work properly, ozone must diffuse freely through the membrane. A coating on the membrane will interfere with the passage of ozone, resulting in slow response. Clean the mem- brane by rinsing it with a stream of water from a wash bottle, or gently wipe the membrane with a soft tissue.

C.Is the sample flow within the recommended range? Gradual loss of sample flow will cause a downward drift.

D.Is the sensor new or has it been recently serviced. New or rebuilt sensors may require several hours to stabilize.

16.8.6 Sensor does not respond to changes in ozone level.

A.Is the grab sample test accurate? Is the grab sample representative of the sample flowing to the sensor?

B.Is the membrane clean? Clean the membrane and replace it if necessary. Check that the holes at the base of the cathode stem are open. Use a straightened paper clip to clear blockages. Replace the electrolyte solution.

C.Replace the sensor.

16.8.7 Ozone readings are too low.

A.Was the sample tested as soon as it was taken? Ozone solutions are highly unstable. Test the sample imme- diately after collecting it.

B.Low readings can be caused by zeroing the sensor before the residual current has reached a stable minimum value. Residual current is the current the sensor generates even when no ozone is in the sample. Because the residual current is subtracted from subsequent measured currents, zeroing before the current is a mini- mum can lead to low results.

Example: The true residual current for an ozone sensor is 4 nA, and the sensitivity is 350 nA/ppm. Assume the measured current is 200 nA. The true concentration is (200-4)/350 or 0.560 ppm. If the sensor was zeroed pre- maturely when the current was 10 nA, the measured concentration will be (200-10)/350 or 0.543 ppm. The error is 3.6%. Suppose the measured current is 100 nA. The true concentration is 0.274 ppm, and the meas- ured concentration is 0.257 ppm. The error is now 6.2%. The absolute difference between the reading remains the same, 0.017 ppm.

C.Sensor response depends on flow. If the flow is too low, readings will be low and flow sensitive. Verify that the flow past the sensor equals or exceeds the minimum value. See the sensor instruction manual for recom- mended flows.

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Contents Model 54eA Amperometric Hart Analyzer/ControllerEssential Instructions Page Model 54eA ANALYZER/CONTROLLER 10.0 11.012.0 13.0Iii List of FiguresSection Title Section Specifications Features and ApplicationsSpecifications General PowerOutput Accuracy ± 0.05 mA Alarms Weight/Shipping Weight 5 lb/6 lb 2 kg/2.5 kgSpecifications Oxygen Specifications Free ChlorineSpecifications Total Chlorine Specifications Ozone24 VDC 115/230 VAC, 50/60 Hz PowerOrdering Information Unpacking and Inspection Section InstallationInstallation Pipe and Wall Mounting Dimensions Pipe mountingPanel Mounting Dimensions Panel mountingGeneral Section WiringPOWER, ALARM, and Output Wiring 454EPH02 General Sensor WiringWiring Model 499A oxygen, chlorine, and ozone sensors 4054eA01 4054eA03 4054eA02 4054eA04 4054eA07 Alarm Status Section Display and OperationGeneral Description DisplaySection Software Configuration Program Settings ListChoices Factory Settings Configure Choices Factory Settings Temperature compensation Section Menu Tree for the 54eA Controller Main Menu Main Alarm setpoints Alarm 2 setpointMA 0.00 ppm 20 mA 20.00 ppm Output 1 12.00 mA Ranging the OutputsAlarm setpoints Output setpointsSimulated test Setpoint 1.000 ppm 4mA 0.000 ppm 20mA 10.00 ppmTest output Test alarm 1 OpenSimulated tests Configure DisplayLanguage English Display left Display right Out Display contrast Timeout OnTemp units C Output 1 mA Output 2 mA Output Measurement OutputsOutput 1 control Ctrl mode Normal Output 1 SetupOutput 1 Control Range 4-20 mA Dampen 0 sec Hold Last ValueHold setup Using holdChanging Alarm Parameters Always configure the control parameters Before makingChanges in the alarm setup Alarm Control SettingsAlarm 1 control Alarm 1 setupAlarm 2 control Alarm Low Setpoint 0.000 ppmLow Alarm High AlarmAlarm Fault Feed limit DisableTimeout 3600 sec Feed limit timer setupAlarm 4 setup Feed limit timer Interval timerTimer Disable Timer Time activated Interval 24.0 hr Interval timer setupPH sensor Enable PH sensor DisableUsing the 499ACL-01 sensor PH comp Manual PH value 7.00 pHAutocal Standard Diagnostics OffGlass imp lo 20 MΩ Temp coeff Operate iso 7.00 pH Sensor iso 7.00 pHTemperature Compensation and Temperature Units Temp comp AutoTemp units C Temp comp Manual Temp units C60 Hz Noise ReductionMain sensor cal Barometric Pressure Bar meas AutoBar units mm Hg Lock program Lock config Noise rejection Main sensor calSecurity Lock allAction Definitions Controller Mode PriorityCondition Definitions Section Calibration Temperature IntroductionAdjust temp + 025.1 C Temperature CalibrationSection Calibration Dissolved Oxygen Dissolved Oxygen ConcentrationSensor must be in zero solution Zeroing the SensorStabilizing . . . Wait Calibrating the Sensor in AIRSection Calibrate 8.32 ppm Calibrating the Sensor Against a Standard InstrumentZero main sensor Adjust temperature Calibrate main sensorStandardize Calibrating Barometric PressureSection Calibration Free Chlorine 499ACL-01 Sensor Current as a Function of Free Chlorine ConcentrationCalibrate main sensor Calibrate 1.100 ppm Full Scale CalibrationDual range cal Output trimCalibrate low point Dual Slope CalibrationLow point 2.000 ppm Calibrate high pointSection Calibration Free Chlorine 498CL-01 IntroductionPpm 100ppm 000 ppm Section Calibration Free Chlorine 498CL-01 Section Calibration Total Chlorine This page intentionally left blank Section Calibration Monochloramine Sensor Current as a Function of Monochloramine ConcentrationPpm 100ppm Section Calibration Ozone Sensor Current as a Function of Ozone ConcentrationPpm 100ppm Section PH at 25C Standards Nominal pHAutocal buffer Automatic TWO-POINT Calibration10.02 pH Manual TWO-POINT Calibration Calibrate pointPt 04.00pH 25C 10.01 pH Pt 4.00pH 25.0CStandardization ONE-POINT Calibration Pt calibration Standardize pH pH slopePH slope 60.00 mV/pH Section Calibration Current Outputs Trimming the OutputsSection PID and TPC Control PID Control CodeProcess Reaction Curve Method Proportional Gain Plus Integral ResetControl Loop Adjustment and Tuning Process Reaction Curve Section Time Proportional Control TPC Mode Code Section Troubleshooting Troubleshooting When a Fault Message is ShowingFault message Explanation See Section OverviewTemperature error low or high High input currentCheck sensor zero PH low or high input voltageTroubleshooting When no Fault Message is Showing Oxygen Problem See SectionSense line open Failure factory and Failure eepromZero reading Is unstable Possible error warning during in-process calibrationZero current is too high Barometric pressure reading is too high or too low Process readings are erraticReadings drift Sensor does not respond to changes in oxygen levelProblem Zero current is unstableSensor can be calibrated, but the current is too low Sensor does not respond to changes in chlorine level Chlorine readings are too lowProblem See Section Sensor does not respond to changes in monochloramine level Readings are too low Troubleshooting When no Fault Message is Showing Ozone Sensor does not respond to changes in ozone level Ozone readings are too lowTroubleshooting When no Fault Message is Showing pH 100 Controller will not accept manual slopeSensor does not respond to known pH changes Process pH readings are noisy 101Troubleshooting not Related to Measurement Problems Problem ActionSimulating Inputs Dissolved Oxygen Sensor Polarizing Voltage Resistance Expected currentSimulating Inputs Other Amperometric Measurements Simulate Chlorine and Ozone 103104 Simulating pH input when the preamplifier is in the sensorVoltage mV PH at 25C 105 Simulating TemperatureSimulating temperature Measuring Reference Voltage 106Section Maintenance Replacement Parts Part Number DescriptionSection Return of Material GeneralWarranty Specifications subject to change without notice