User Manual

MON20/20 Software for Gas Chromatographs

3-9000-745

OCTOBER 2010

 

 

B.2 Peak detection

For normal area or peak height concentration evaluation, the determination of a peak's start point and end point is automatic. The manual determination of start and end points is used only for area calculations in the Forced Integration mode. Automatic determination of peak onset or start is initiated whenever Integrate Inhibit is turned off. Analysis is started in a region of signal quiescence and stability, such that the signal level and activity can be considered as baseline values.

Note

The controller assembly software assumes that a region of signal quiescence and stability will exist.

Having initiated a peak search by turning Integrate Inhibit off, the controller assembly performs a point by point examination of the signal slope. This is achieved by using a digital slope detection filter, a combination low pass filter and differentiator. The output is continually compared to a user-defined system constant called Slope Sensitivity. A default value of 8 is assumed if no entry is made. Lower values make peak onset detection more sensitive, and higher values make detection less sensitive. Higher values (20 to 100) would be appropriate for noisy signals, e.g. high amplifier gain.

Onset is defined where the detector output exceeds the baseline constant, but peak termination is defined where the detector output is less than the same constant.

Sequences of fused peaks are also automatically handled. This is done by testing each termination point to see if the region immediately following it satisfies the criteria of a baseline. A baseline region must have a slope detector value less than the magnitude of the baseline constant for a number of sequential points. When a baseline region is found, this terminates a sequence of peaks.

A zero reference line for peak height and area determination is established by extending a line from the point of the onset of the peak sequence to the point of the termination. The values of these two points are found by averaging the four integrated points just prior to the onset point and just after the termination points, respectively.

B-2

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Emerson Process Management 3-9000-745 manual Peak detection

3-9000-745 specifications

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