Instruction Manual

IM-106-910Xi, Original Issue November 2010

Xi Advanced Electronics

Stoichiometer

Process upsets can sometimes cause a combustion process to go into

 

sub-stoichiometric or reducing conditions. The oxygen readings from one or

 

more probes may decline all the way to zero. The stoichiometer cell will

 

measure the amount of oxygen deficiency during these reducing conditions.

 

The trends in your DCS can be set up for a lower range limit of -1 or -2%

 

oxygen to depict the level of oxygen deficiency.

 

The operator can see if his control recovery actions are having the desired

 

effect. These types of events do not occur frequently, but knowing the

 

parameters of the situation prevents over-correcting while coming out of the

 

reducing condition.The stoichiometer feature requires purchasing the acid

 

resistant stoichiometer cell and the stoichiometer feature inside the Xi.

 

 

 

NOTE

 

Make sure the DCS is configured for the same range as the Xi. For instance:

 

-1% O2 to 10% O2.

Programmable

The zirconium oxide sensing technology has historically measured process

Reference

oxygen by using ambient or instrument air as a reference (20.95% oxygen).

 

The sensor develops most of its signal at the low oxygen levels typically found

 

in combustion flue gasses (2-4% oxygen), and is most accurate at these

 

levels. When measuring near 20.95% O2, the sensor develops only a few

 

millivolts of signal, and accuracy degrades.

 

The programmable reference feature permits the user to use a bottled

 

reference gas of low oxygen value (0.4% oxygen recommended). When

 

measuring at or near 21% oxygen, a strong negative oxygen signal results,

 

with much improved accuracy. A bottle of reference gas typically lasts about a

 

month at the low flows required. Typical applications would be:

 

Flue gas recirculation - controlling the mixing of flue gasses into the burner

 

windbox prior ahead of the burner to reduce NOx emissions.

 

Moisture monitoring - measuring the amount of moisture coming off of

 

industrial dryers by noting the dilution effect water vapor has on the normal

 

20.95% ambient drying air. (Non-combustion drying processes only.)

 

Enriched oxygen concentration - pure oxygen is sometimes mixed in with

 

the combustion air to increase heat at the flame. This is used in steel and

 

other metals reduction processes and in some catalyst regenerators.

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Emerson Process Management IM-106-910Xi instruction manual Stoichiometer, Programmable, Reference