S H A R P

Date Revised:

Date Issued :May. 28, 1999

MATERIAL SAFETY DATA SHEET (1/2)

MSDS No. B-1020

Section 1. Product Identification

Product : FO-47ND / DUNT-455BSCZZ (Toner Cartridge)

Section 2. Supplier's Name and Address

Sharp Corporation

22-22 Nagaike-cho, Abeno-ku, Osaka, Japan

Local suppliers are listed below. Please contact the nearest supplier for additional information.

 

(Country)

(Name and Telephone Number)

 

 

 

 

 

 

U.S.A.

Sharp Electronics Corporation

 

 

 

Telephone number for information: 1-800-237-4277

 

 

 

Emergency telephone number : 1-800-255-3924

 

 

Canada

Sharp Electronics of Canada Ltd.

 

 

 

Telephone number for information: 905-890-2100

 

 

 

Emergency telephone number : 1-800-255-3924

 

 

 

 

 

Section 3. Ingredients

Ingredients

CAS No.

Proportion

OSHA PEL

ACGIH TLV

Other Limits

Polyester resin

(NJ TSRN 361615-5042-P)

>90%

Not listed

Not listed

None

Carbon black

1333-86-4

1 - 5%

3.5 mg/m3

3.5 mg/m3

TWA(Austl) : 3 mg/m3

Polyolefin wax

9003-07-0

1 - 5%

Not listed

Not listed

None

Polyolefin wax

25722-45-6

(TOTAL OF BOTH)

Not listed

Not listed

None

Organic pigment

(NJ TSRN 361615-5025-P)

1 - 5%

Not listed

Not listed

None

Section 4. Hazardous Identification (Emergency Overview)

Toner is a fine, black powder possessing no immediate hazard. There are no anticipated carcinogenic effects from exposure based on animal tests performed using toner. When used as intended according to instructions, studies do not indicate any symptoms of fibrosis will occur.

Section 5.Health Hazard Data

Route(s) of Entry :

Inhalation?

Skin?

Ingestion?

Health Hazard :

Yes

Yes(Eye contact)

Yes

 

 

 

Inhalation, LC50(g/m3 /4h) :

>0.74(Rats)* (This was the highest attainable concentration.)

Ingestion (oral), LD50(mg/kg) :

>5000 (Rats) *

 

 

Dermal, LD50 (mg/kg) :

>2000 (Rats) *

 

 

Eye irritation :

Not an irritant (rabbits) *

 

Skin irritation :

Not an irritant (rabbits) *

 

Skin sensitizer :

No data available

 

 

Mutagenicity :

Negative * (AMES test)

 

 

(* = Based on data for other products with similar ingredients)

Carcinogenicity : In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible human carcinogen). This classification is given to chemicals for which there is inadequate humanevidence, but sufficient ani- mal evidence on which to base an opinion of carcinogenicity. Theclassification is based upon the devel- opment of lung tumors in rats receiving chronic inhalationexposures to free carbon black at levels that induce particle overload of the lung. Studiesperformed in animal models other than rats did not show any association between carbon black and lung tumors. Moreover, a two-year cancer bioassay using a typical toner preparation containing carbon black demonstrated no association between toner exposure and tumor development in rats.

Chronic Effect : Prolonged inhalation of excessive dust may cause lung damage. It is attributed to “lung overloading”, a generic response to excessive amounts of any dust retained in the lungs for a prolonged interval. Use of this product as intended does result in inhalation of excessive dust. In a study in rats by chronic inhala- tion exposure to a typical toner, a mild to moderate degree of lung fibrosis was observed in 92% of rats in the high concentration (16mg/m3 ) exposure group, and a minimal to mild degree of fibrosis was noted in 22% of the animals in the middle (4mg/m3 ) exposure group. But no pulmonary change was reported in the lowest (1mg/m3 ) exposure group, the most relevant level to potential human exposures.

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Sharp FO-4650, FO-4970 operation manual A R P