Engineering Control/Ventilation: Work/Hygienic Practice:
Steps to be taken in case of Spill or Leak:
Waste Disposal Method:
Contaiminated Packaging:

SHARP

MATERIAL SAFETY DATA SHEET

UX5000U MSDS

Date Issued: 1996. 8. 1

MSDS No. B-1008

Section 1. Product Identification

Product Code:

FO-50ND

Toner Cartridge

Section 2. Supplier’s Name and Address

Sharp Corporation

22-22 Nagaike-cho, Abeno-ku, Osaka, Japan

Local suppliers are listed below. Please contact the nearest supplier for additional information.

 

 

 

 

 

 

(Country)

(Name and Telephone Number)

 

 

 

U.S.A.

Sharp Electronics Corporation

 

 

 

 

Telephone number for information :

201-529-8200

 

 

Emergency telephone number

:

1-800-255-3924

 

Canada

Sharp Electronics of Canada Ltd.

 

 

 

 

Telephone number for information :

416-890-2100

 

 

Emergency telephone number

:

1-800-424-9300

 

United Kingdom

Sharp Electronics(U.K.)Ltd.

 

 

 

 

Telephone number for information :

01923-474013

Section 3. Ingredients

Ingredients

 

CAS No.

Proportion

OSHA PEL

ACGIH TLV

Other Limits

Polyester resin

 

361615-5042-P

>85 %

3.5mg/m3

3.5mg/m3

 

Carbon black

1333-86-4

1-5

%

 

Polypropylene

9003-07-0

1-5

%

 

 

 

Organic pigment

 

361615-5025-P

1-5

%

 

 

 

Section 4. Hazardous Identification (Emergency Overview)

Toner is a fine, black powder prossessing no immediate hazard. There are no anticipated carcinogenic effects from exposure based on animal tests performed using toner. When used as intended according to instructions, syudies do not indicate any symptoms of fibrosis will occur.

Section 5. Health Hazard Data

Route(s) of Entry:

Eye contact, inhalation, ingestion

Health Hazards:

No data available

Carcinogenicity:

In 1996 the IARC reevaluated carbon black as a Group 28 carcinogen (possible human carcinogen). This classification is given to chemicals for which there is

 

inadequate human evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity. The classification is based upon the development of lung

 

tumors in rats receiving chronic inhalation exposures to free carbon black at levels that induce particle overload of the lung. Studies performed in animal models other

 

than rats did not show any association between carbon black and lung tumors. Moreover, a two-year cancer bioassay using a typical toner preparation containing carbon

 

black demonstrated no association between toner exposure and tumor development in rats.

Signs and Symptoms of Exposure:

No symptoms expected under intended use.

Medical Conditions Generally Aggravated by Exposure: None

Choronic effect:

In a study in rats of chronic inhalation exposure to a typical toner, a mild to moderate degree of lung fibrosis was observed in 92% of the rats in the high concentration

 

(16mg/m3) exposure group, and a minimal to mild degree of fibrosis was noted in 22% of the animals in the middle (4mg/m3) exposure group, but no pulmonaly change

 

was reported in the lowest (1mg/m3) exposure group, the most relevant level to potential human exposures.

Emergency and First Aid Porcedures:

 

Inhalation:

If symptoms are experienced, remove source of contaimination or move victim to fresh air and obtain medical advice.

Eye Contact:

Do not allow victim to rub eye(s). Flush with gently flowing water (lukewarm preferable) for 15 minutes or untill particle is removed. Have victim look right and left,

 

and, then up and down. If irritation does occur, obtain medical attention. DO NOT attempt to manually remove anything stuck to the eye(s).

Ingestion:

If irritation or discomfort occur, obtain medical attention immediately.

Section 6. Physical Chemical Characteristics

Boiling/Melthing Point:

N.AP.

Specific Gravity:

1.2

Vapor Pressure:

N.AP.

Solubility In Waster:

Negligible

Vapor Density:

N.AP.

PH:

N.AP.

Evaporation Rate:

N.AP.

Viscosity:

N.AP.

Appearance:

powder

Color:

Black

Odor:

oder

 

 

Section 7. Fire and Explosion Data

Flash Point (Method Used):

N.AP.

 

Ignition Temperature:

450°C

 

Flammable Limits:

(LEL); N.AP.

(UEL); N.AP.

Extinguishing Media:

CO2, water spray, foam and dry chemical

Special Fire Fighting Procedure:

None

 

Unusual Fire and Explosion Hazard:

If dispersed in air, like most finely divided organic powders, may form an explosive mixture.

Sensitivity to Mechanical Impact:

None

 

Sensitivity to Static Charge:

None

 

Section 8. Reactivity Data

Stability:

Stable

Incompatibility (Materials to Avoid):

Oxidizing materials

Hazardous Decomposition:

CO, CO2

Hazardous Polymerization:

None

Section 9. Precautions for Safe Handling and Use

Personal Protection Information (Respiratory, Eye Protection and Protective Glove):

Use of a dust mask is recommended when handling a large quantity of toner or during long term exposure, as with any non-toxic dust. None required under intended use.

Inhalation should be minimized as with any non-toxic dust.

Wipe off with paper or cloth. DO NOT use vacuum cleaner when released a large amount. It, like most finely divided organic powders, may create a dust explosion. Preparation (community provisions): Waste may be disposed or incinerated under conditions which meet all federal, state and local environmental regulations. Waste may be disposed or incinerated under conditions which meet all federal, state and local environmental regulations.

Section 10. Regulatory Information

NFPA Rating (U.S.A.):

Health = 1

Flammability = 1

Reactivity = 0

WHMIS Legislation (Canada):

None

 

 

Transport Information:

None

 

 

UN No.:

None listed.

 

 

Section 11. Other Information

Reference:

IARC (1996)

 

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol. 65, Printing Process and Printing inks, Carbon Black and Some Nitro

 

Compounds, Lyon, pp-149-261

 

H. Muhle, B. Bellmann, O. Creutzenberg, C. Dasenbrock, H. Ernst, R. Kilpper, J. C. Mackenzie, P. Morrow, U. Mohr, S. Takenaka, and R. Mermelstein (1991) Pulmonary

 

Response to Toner upon Chronic Inhalation Exposure in Rats.

 

Fundamental and Applied Toxicology 17, pp. 280-299

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

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Sharp UX-5000 operation manual Sharp