MODEL 3081 pH/ORP

SECTION 16.0

 

GLOSSARY

Combination electrode

In a combination electrode, the measuring electrode and reference electrode are

 

combined in a single body. Often the temperature element is included in the body

 

as well.

Common

A point in a circuit against which voltages are measured.

Diagnostics

Diagnostics, also called advanced sensor diagnostics, automatically and continu-

 

ously monitor the condition of the sensor. Diagnostics warn the user of impending

 

or existing problems with the sensor. The most useful pH sensor diagnostics are

 

glass impedance and reference impedance.

Electrode potential

Electrode potential is a measure of the tendency of a half reaction to occur as writ-

 

ten. Electrode potentials are stated relative to a reference electrode, which by

 

convention is the normal hydrogen electrode. The normal hydrogen electrode is

 

assigned a potential of zero volts.

Electrochemical cell

An electrochemical cell consists of two half reactions occurring in separate con-

 

tainers connected electrically by a salt bridge. The electrons produced by the oxi-

 

dation half reaction are consumed by the reduction half reaction. Because the

 

electrons must pass through an external circuit, they can be made to do useful

 

work. The drawing below shows a simple electrochemical cell.

 

 

 

 

 

 

 

The voltage of the electrochemical cell (measured without drawing current from

 

the cell) is the algebraic sum of the potentials of the two electrodes.

Electrode

Electrochemistry is the study of charge transfer across boundaries. The charge

 

being transferred can be ions or electrons. An electrode is a two-phase system

 

where the charge transfer across the interface involves electrons. A real physical

 

electrode may incorporate several boundaries.

Electrolyte

An electrolyte is a substance that when dissolved in water produces an apprecia-

 

ble concentration of ions. Most salts, mineral acids (sulfuric acid, hydrochloric

 

acid, phosphoric acid, and nitric acid), and most bases are electrolytes.

Error

Error is a measure of how closely a measured value agrees with the true value.

 

In cases where a true value is not known, error usually refers to the difference

 

between the measured and the generally accepted value.

Error condition

An error condition (Std Err, SLOPE Err LO, or SLOPE Err HI) occurs during cali-

 

bration if standardization offset or the slope exceeds programmed values.

Explosion proof

An enclosure is explosion proof if it can withstand an internal explosion without

 

rupturing and without causing the the ignition of the gas surrounding the enclo-

 

sure.

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Emerson Process Management 3081 pH/ORP instruction manual 129