4220 Flow Meter

Appendix D General Safety Procedures

D.3 Hazardous Gases

number of harmful vapors. They, too, are sensed by smell and explosimeter tests if they get into the public sewer. Such occur- rences are rare.

“The attempt to instill a sense of urgency about real hazards is diluted if a man is told to give attention to a long list of things that in fact are irrelevant.

“Be very careful to avoid high H2S concentrations, flammable atmospheres, and hazards of physical injuries. Remember that much H2S may be released by the stirring up of sludge in the bottom of a structure. Obey your senses in respect to irritating gases, such as chlorine (unconsciousness comes suddenly from breathing too much). Be cautious about strange odors. Do not determine percent oxygen in the air. There is a danger that the result will influence a man's thinking about the seriousness of the real hazards. Most important, use ample ventilation, and do not enter a potentially hazardous structure except in a good safety harness with two men at the top who can lift you out.”

The following table contains information on the properties of hazardous gases.

Table D-1 Hazardous Gases

 

 

 

Specific

 

Max

Max. Safe

Explosive

Likely

 

Simplest and

 

 

 

Gravity

 

Range (% by

Location

Most

 

Chemical

Common

Physiological

Safe 60

8 Hour

Cheapest

Gas

or Vapor

vol. in air)

of

Common

Formula

Properties

Effect

Min. Exposure

Exposure

Safe Method

 

Density

Limits

Highest

Sources

 

 

 

 

ppm

ppm

of Testing

 

 

 

Air =1

 

lower/upper

Concentration

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Ammonia

NH3

Irritant and

0.60

Causes throat

300

85

16

25

Near top.

Sewers,

Detectable

 

 

poisonous. Col-

 

and

to

 

 

 

Concentrates

chemical

odor at low

 

 

orless

 

eye irritation at

500

 

 

 

in closed up-

feed

concentrations

 

 

with characteris-

 

0.05%, cough-

 

 

 

 

per spaces

rooms.

 

 

 

tic

 

ing

 

 

 

 

 

 

 

 

 

odor.

 

at 0.17%. Short

 

 

 

 

 

 

 

 

 

 

 

exposure at

 

 

 

 

 

 

 

 

 

 

 

0.5%

 

 

 

 

 

 

 

 

 

 

 

to 1% fatal.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Benzene

C6H6

Irritant, colorless

2.77

Slight symp-

3,000

25

1.3

7.1

At bottom.

Industrial

Combustible

 

 

anesthetic

 

toms

to

 

 

 

 

wastes,

gas indicator

 

 

 

 

after several

5,000

 

 

 

 

varnish,

 

 

 

 

 

hours

 

 

 

 

 

solvents.

 

 

 

 

 

exposure at

 

 

 

 

 

 

 

 

 

 

 

0.16% to 0.32%.

 

 

 

 

 

 

 

 

 

 

 

2% rapidly

 

 

 

 

 

 

 

 

 

 

 

fatal.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Carbon

CS2

Nearly odorless

2.64

Very poison-

15

1.3

44.0

At bottom

An insecti-

Combustible

Bisulfide

 

when pure, color-

 

ous,

 

 

 

 

 

cide

gas indicator

 

 

less, anesthetic.

 

irritating, vom-

 

 

 

 

 

 

 

 

 

Poisonous.

 

iting,

 

 

 

 

 

 

 

 

 

 

 

convulsions,

 

 

 

 

 

 

 

 

 

 

 

psychic distur-

 

 

 

 

 

 

 

 

 

 

 

bance.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

D-6

Page 178
Image 178
Teledyne 4220 installation and operation guide Table D-1 Hazardous Gases