4220 Flow Meter

Appendix D General Safety Procedures

 

 

 

Table D-1 Hazardous Gases (Continued)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Specific

 

Max

Max. Safe

Explosive

Likely

 

Simplest and

 

 

 

Gravity

 

Range (% by

Location

Most

 

Chemical

Common

Physiological

Safe 60

8 Hour

Cheapest

Gas

or Vapor

vol. in air)

of

Common

Formula

Properties

Effect

Min. Exposure

Exposure

Safe Method

 

Density

Limits

Highest

Sources

 

 

 

 

ppm

ppm

of Testing

 

 

 

Air =1

 

lower/upper

Concentration

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Gas

Chemical

Common

Specific

Physiological

Max

Max.

Explosive Range

Likely

Most

Simplest and

 

Formula

Properties

Gravity or

Effect*

Safe

Safe

(% by vol.

Location

Common

Cheapest

 

 

 

Vapor

 

60 Min.

8 Hour

in air.)

 

of

Sources

Safe Method

 

 

 

Density

 

Exposure

Exposure

Limits

 

Highest

 

of Testing

 

 

 

Air = 1

 

ppm

ppm

lower/upper

Concentration

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Hydro-

H2S

Irritant and poi-

1.19

Impairs sense

200

20

4.3

 

Near bottom,

Coal gas,

1. H2S

gen Sul-

 

sonous volatile

 

of smell, rap-

to

 

 

 

but may be

petro-

Ampoule.

fide

 

compound. Rot-

 

idly as concen-

300

 

45.0

 

above bottom if

leum,

 

 

 

ten egg odor in

 

tration

 

 

 

 

air is heated and

sewer gas.

2. 5% by weight

 

 

small concentra-

 

increases.

 

 

 

 

highly humid.

Fumes

lead acetate

 

 

tions. Exposure

 

Death in few

 

 

 

 

 

from blast-

solution.

 

 

for 2 to 15 min. at

 

minutes at

 

 

 

 

 

ing under

 

 

 

0.01% impairs

 

0.2%. Exposure

 

 

 

 

 

some con-

 

 

 

sense of smell.

 

to 0.07 to 0.1%

 

 

 

 

 

ditions.

 

 

 

Odor not evident

 

rapidly causes

 

 

 

 

 

Sludge gas.

 

 

 

at high concen-

 

acute poison-

 

 

 

 

 

 

 

 

 

trations. Color-

 

ing. Paralyzes

 

 

 

 

 

 

 

 

 

less. Flammable.

 

respiratory

 

 

 

 

 

 

 

 

 

 

 

center.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Methane

CH4

Simple asphyx-

0.55

Acts mechani-

Probably no limit,

5.0

15.0

At top, increas-

Natural

1. Combustible

 

 

iant.

 

cally to deprive

provided oxygen

 

 

 

ing to certain

gas, sludge

gas indicator

 

 

Colorless, odor-

 

tissues of oxy-

percent-age is suf-

 

 

 

depth.

gas, manu-

 

 

 

less, tasteless,

 

gen. Does not

ficient for life.

 

 

 

 

factured

2. Oxygen defi-

 

 

flammable.

 

support life.

 

 

 

 

 

gas, sewer

ciency indica-

 

 

 

 

 

 

 

 

 

 

gas. Strata

tor.

 

 

 

 

 

 

 

 

 

 

of sedi-

 

 

 

 

 

 

 

 

 

 

 

mentary

 

 

 

 

 

 

 

 

 

 

 

origin. In

 

 

 

 

 

 

 

 

 

 

 

swamps or

 

 

 

 

 

 

 

 

 

 

 

marshes.

 

 

 

 

 

 

 

 

 

 

 

 

 

Nitrogen

N2

Simple asphyx-

0.97

Physiologically

Near top, but

Sewer gas.

Oxygen

 

 

iant. Colorless,

 

inert.

 

 

 

 

may be found

sludge gas.

deficiency

 

 

tasteless.

 

 

 

 

 

 

near bottom.

Also issues

indicator.

 

 

Non-flammable.

 

 

 

 

 

 

 

from some

 

 

 

Principal constit-

 

 

 

 

 

 

 

rock strata.

 

 

 

uent of air. (about

 

 

 

 

 

 

 

 

 

 

 

79%).

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Nitrogen

NO

Colorless

1.04

60 to 150 ppm

50

10

Near bottom.

Industrial

NO2 detector

Oxides

 

 

 

cause irritation

 

 

 

 

 

wastes.

tube.

 

N2O

Colorless,

 

and coughing.

 

 

 

 

 

Common

 

 

 

sweet odor.

1.53

 

 

 

 

 

 

air pollut-

 

 

 

 

 

Asphyxiant.

 

 

 

 

 

ant.

 

 

NO2

Reddish-brown.

1.58

 

 

 

 

 

 

 

 

 

 

Irritating odor.

 

100 ppm dan-

 

 

 

 

 

 

 

 

 

Deadly poison

 

gerous.

 

 

 

 

 

 

 

 

 

 

 

200 ppm fatal.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Oxygen

O2

Colorless, odor-

1.11

Normal air con-

Variable at dif-

Oxygen

Oxygen defi-

 

 

less, tasteless.

 

tains 20.8% of

 

 

 

 

ferent levels.

depletion

ciency indica-

 

 

Supports com-

 

O2. Man can tol-

 

 

 

 

 

from poor

tor.

 

 

bustion.

 

erate down to

 

 

 

 

 

ventila-

 

 

 

 

 

12%. Minimum

 

 

 

 

 

tion and

 

 

 

 

 

safe 8 hour

 

 

 

 

 

absorp-

 

 

 

 

 

exposure, 14 to

 

 

 

 

 

tion, or

 

 

 

 

 

16%. Below 10%,

 

 

 

 

 

chemical

 

 

 

 

 

dangerous to

 

 

 

 

 

consump-

 

 

 

 

 

life. Below 5 to

 

 

 

 

 

tion of

 

 

 

 

 

7% probably

 

 

 

 

 

oxygen.

 

 

 

 

 

fatal.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Ozone

O3

Irritant and poi-

1.66

Max. naturally

0.08

0.04

Near bottom.

Where

Detectable

 

 

sonous. Strong

 

occurring level

 

 

 

 

 

ozone is

odor

 

 

electrical odor.

 

is 0.04 ppm.

 

 

 

 

 

used for

at 0.015 ppm.

 

 

Strong oxidizer.

 

0.05 ppm

 

 

 

 

 

disinfec-

 

 

 

Colorless. At 1

 

causes irrita-

 

 

 

 

 

tion.

 

 

 

ppm, strong sul-

 

tion of eyes and

 

 

 

 

 

 

 

 

 

fur-like odor.

 

nose. 1 to 10

 

 

 

 

 

 

 

 

 

 

 

ppm causes

 

 

 

 

 

 

 

 

 

 

 

headache, nau-

 

 

 

 

 

 

 

 

 

 

 

sea; can cause

 

 

 

 

 

 

 

 

 

 

 

coma. Symp-

 

 

 

 

 

 

 

 

 

 

 

toms similar to

 

 

 

 

 

 

 

 

 

 

 

radiation dam-

 

 

 

 

 

 

 

 

 

 

 

age.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

D-8

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Teledyne 4220 installation and operation guide N2O