Conductivity/Resistivity Analyzer/Controller

8.6 Determining and Entering the TDS Conversion Factor

Introduction

The 9782 always measures conductivity. However, the process value can be displayed in terms of total dissolved solids (TDS). If a TDS solution temperature compensation type was specified during I/O setup, then the calibration menu will contain items used to enter the TDS conversion factor for each cell.

Determining TDS conversion factor

To determine the TDS conversion factor, it is first necessary to establish the total dissolved solids in a representative sample of the process. The formal determination of TDS is a laboratory standard method performed on a weighed grab sample of the process fluid. To summarize how a obtain a TDS value:

Suspended solids, if present, are filtered out.

All water is evaporated.

The residue is dried and weighed.

The result is divided by the original sample weight to obtain ppm TDS.

For detailed guidance in determining the official TDS, see “Standard Methods for the Examination of Water and Wastewater,” jointly published by the American Public Health Association, American Water Works Association and Water Pollution Control Federation, Washington, DC.

To determine the conversion factor needed by the 9782 Analyzer/Controller, first use the laboratory procedure summarized above to give an official TDS value. Next divide the TDS value by the conductivity of the sample to yield the conversion factor for that particular process fluid. The conversion factor is then entered into the 9782 to normalize the TDS readout.

With power plant cation conductivity measurements, ion chromatography results may be used to establish the conversion factor for readout in ppb chloride or sulfate ion. Nominal values are 83 ppb per μS/cm for chloride ion and 111 ppb per μS/cm for sulfate ion. The 9782 does not provide temperature compensation in TDS for chloride or sulfate ions.

Out-of range-values forced to closest limit

As long as the entered TDS value is within the acceptable limits for a given cell constant, the value is accepted by the Analyzer/Controller. If a value is outside the accepted range, the unit will not display an error message; instead it will force the value to either the high or low limit of the range of the cell constant. See Table 5-10 for TDS conversion factor defaults.

Calibrate the Analyzer/Controller before entering TDS conversion factor

If you intend to enter a cal factor or use calibration trim, do so before entering the TDS conversion factor as described here.

If you use calibration trim, first set the solution temperature compensation in I/O setup to the non-TDS choice for your process. For example, if you plan to use “NaCl (TDS)” set the solution temperature compensation type to “NaCl” temporarily for calibration purposes. (Solution temperature compensation type is the one I/O setup parameter that can be changed without triggering a cold reset.)

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9782 Series Conductivity/Resistivity Analyzer/Controller - Operator’s Manual

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Honeywell 9782 Series manual Determining and Entering the TDS Conversion Factor, Determining TDS conversion factor