M9110T Date 11/15/13
Teledyne Electronic Technologies
 Copyright 2013 Teledyne Analytical Instruments
Model 9110T NOx Analyzer
 Model 9110T- Standard Touch Screen Version
Model 9110TH NOx Analyzer Specific Configuration
 Rear Panel Gas Fittings
Model 9110T NOx AnalyzerSpecific Configuration
Mounting Options
Pump Mounting Options
 Background Gas
This option includes two concentration alarm relays
 Model 9110T NOx Analyzer Specific Configuration
 Or by accessing various service options on our website at
Safety Messages
Model 9110TH NOx Analyzer Safety Messages
Customer Service Department
 Consignes DE Sécurité
Model 9110T NOx Analyzer Safety Messages
Mise EN Garde
 Organization
Instrument and possibly invalidate the warranty
Maintenance of the analyzer or its parts
About this Manual
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 Table of Contents
 Model 9110T NOx Analyzer Table of Contents
 Model 9110TH NOx Analyzer Table of Contents
 285
 Appendix a Version Specific Software Documentation
 Figures
 229
 Ventilation Clearance
Tables
 325
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 Model 9110TH NOx Analyzer Part
Part General Information
 Model 9110T NOx Analyzer Part
 Overview
Features
Model 9110TH NOx Analyzer Introduction
 Analyzer Options Description/Notes Reference Number
Documentation
Options
Model 9110T NOx Analyzer Introduction
 Ambient Zero and Pressurized Span Valves
Option Description/Notes Reference Number
9110T Analyzer Weighs about 18 KG 40 Pounds
Ambient Zero and Ambient Span Valves
 USB Port For remote connection
 9110T Basic Unit Specifications Parameter
Specifications
Specification
 Software Settings for EPA Equivalence Parameter
Parameter Specification
EPA Equivalency Designation
 North American
Approvals and Certifications
Other Type Certifications
Calibration
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 Model 9110TH NOx Analyzer Getting Started
Instrument warranty. Refer to for more information on
Under Customer Support Return Authorization
Unpacking the 9110T Analyzer
 10 cm / 4
Instrument Layout
Ventilation Clearance
Model 9110T NOx Analyzer Getting Started
 Front Panel Layout
Front Panel
 Display Screen and Touch Control
Buttons
 Field Description/Function
Display Screen and Touch Control Description
 Actual display
 Provides a description of each component on the rear panel
Rear Panel
 Internal Chassis Layout
 Internal Layout Top View with IZS Option
 Internal Layout Top View Showing Other Options
 Electrical Connections
Connections and Setup
Connecting Power
Connecting Analog Inputs Option
 Analog Input Pin Assignments
Connecting Analog Outputs
PIN Description DAS Parameter
 Test Channel
Current Loop Analog Outputs Option 41 Setup
 Current Loop Option Installed on the Motherboard
 10 Status Output Connector Status Output Pin Assignments
Connecting the Status Outputs
 On Condition
Connecting the Control Inputs
Diag Mode
Input #
 Alarm 1 Relay
Concentration Alarm Relay Option
Alarm 2 Relay & Alarm 3 Relay
 Alarm 4 Relay
Connecting the Communications Interfaces
 Anything other than Multidrop communication
Configuration Section
Before using
Communication
 13 Rear Panel Connector Pin-Outs for RS-232 Mode
 Using
 ∙ Parity None
RS-485 operation
RS-232 Multidrop Option 62 Connection
 15 Jumper and Cables for Multidrop Mode
 Time, each by its unique ID see above
Host
Analyzer
Last Analyzer
 Pneumatic Connections
Testing it before setting up the rest of the chain
RS-485 Connection
 Cc3/min x
Been made check all pneumatic fittings for leaks using
Procedures defined in Section
About Zero Air and Calibration Span Gas
 NIST-SRM Type Nominal Concentration
Cylinders
Available
Calibration Span GAS
 Span GAS for Multipoint Calibration
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 Sample GAS Source
Connect a sample gas line to the Sample inlet
Calibration GAS Sources
 Exhaust Outlet
Pneumatic Layout for Basic Configuration
13.3.13.2 or 13.3.13.3 for detailed check if leak suspected
Venting
 This valve package includes
19 Pneumatics, Basic Configuration
 20 Rear Panel Layout with Z/S Valve Options OPT 50A
Attach a sample inlet line to the Sample inlet fitting
 13.3.12
 Mode Valve Condition Valve Port Status Sample
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 Attach a line to the SPAN2/VENT outlet. It should be
 Pneumatic Layout for Ambient ZERO/PRESSURIZED Span OPT 50B
 Mode Valve Condition Valve Port Status
10 Valve Operating States OPT 50B installed
Zero Scrubber and Internal Span Source IZS OPT 50G
 Nitric Acid and the Chemistry of NO2 Permeation Tubes
Internal Span GAS Generation
 Pneumatic Layout for Zero Scrubber and IZS OPT 50G
 Ammonia Removal Sample Conditioner OPT 86A
Gas Conditioner Options
Zero AIR Scrubber OPT 86C, for Z/S Valves
 Model 9110TH NOx Analyzer Getting Started
 Start UP
STARTUP, Functional CHECKS, and Initial Calibration
 Model 9110TH NOx Analyzer Getting Started
 12 Possible Warning Messages at Start-Up
 Initial Calibration
Functional Checks
 Interferents for NOX, no and NO2 Measurements
Following procedure assumes that
Calibration on the analyzer
 Verifying the Reporting Range Settings
 Verifying the Expected NOX and no Span GAS Concentration
Verify the Precise Concentration Value of the Span gases
Independently
No x Must be identical
 Model 9110TH NOx Analyzer Getting Started
 Initial ZERO/SPAN Calibration Procedure
Improving our service and our products. Thank YOU
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Page
 Part Operating Instructions
 Model 9110T NOx Analyzer Part
 An allowable value, the Entr button will re-appear
Model 9110TH NOx Analyzer Overview of Operating Modes
 Analyzer Operating Modes
Sample Mode
Test Functions
Model 9110T NOx Analyzer Overview of Operating Modes
 Samp
To view these Test functions, press
 Viewing 9110T Test Functions
Absolute atmospheric pressure
 Cannot DYN Span
System Reset
Cannot DYN Zero
 Setup Mode
Calibration Mode
 Primary Setup Mode Features and Functions
Password Security
Primary Setup Menu
Secondary Setup Menu Setup MORE
 Entered value had not been accepted
 Model 9110TH NOx Analyzer Setup Menu
Setup  CFG Configuration Information
Setup ACAL Automatic Calibration Option
Setup DAS Internal Data Acquisition System
 Analog Output Reporting Ranges
Setup RNGE Analog Output Reporting Range Configuration
Model 9110T NOx Analyzer Setup Menu
Physical Ranges
 Analog OUT
When switching between reporting range modes, Always check
For the other modes
 Reset the upper range limits for the new mode selection
Analog Output Reporting Range Default Settings
 IND Mode Analog Output Assignments
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 High physical ranges referred to in Section
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 Importantimpact on Readings or Data
Setup  Rnge  DIL Using the Optional Dilution Ratio Feature
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 Password Level
Setup  Pass Password Protection
To enable passwords, press
Password Levels
 Has to press Entr to access the password-protected menus
 Setting the Time of DAY
Setup  CLK Setting the Internal TIME-OF-DAY Clock
 Adjusting the Internal CLOCK’S Speed
 ID Machine Identification
Setup  Comm Communications Ports
 COM1COM2 MODE, Baude Rate and Test Port
Setup  Vars Variables Setup and Definition
Use the SETUPCOMMCOM1COM2 menus to
Inet Ethernet
 OFF
Allowed Vars Variable Description Default Values
Auto
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 Setup  Diag Diagnostics Functions
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 Stsystemok = on
STSYSTEMOK=ON
 Analog Output Diag Aout
Analog I/O Configuration Diag AIO
 Accessing the Analog I/O Configuration Submenus
To access the Analog I/O Configuration sub menu, press
 Range Name Range Span Minimum Output Maximum Output
Analog Output Voltage Range Min/Max
Curr
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 Automatic Individual Calibration of the Analog Outputs
Analog output is enabled. See Section
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 Adjusted. See Section
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 Current Loop Output Check
Turning AN Analog Output OVER-RANGE Feature ON/OFF
 Adding a Recorder Offset to AN Analog Output
 Model 9110TH NOx Analyzer Setup Menu AIN Calibration
 SET Exit
External Analog Inputs XIN1…XIN8 Option Configuration
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 Test functions available to be reported are listed in Table
 To activate the Test Channel and select a function, press
Optic Test
 Changes with low-level calibration
Electrical Test
Ozone GEN Override
Flow Calibration
 MODE1
Communication MODES, Baud Rate and Port Testing
Data Terminal / Communication Equipment DTE DEC
Communication Modes
 Model 9110T NOx Analyzer Communications Setup and Operation
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 COM Port Baud Rate
COM Port Testing
 Communications Menu
Sample RANGE=500.0 PPB NOX= TST TST CAL Setup
Setup X.X Primary Setup Menu
Secondary Setup Menu Comm Vars
 LED Function
To configure Ethernet communication manually
Ethernet Status Indicators
Ethernet
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 Default Ethernet setting is Dhcp
 Access the Communications Menu SETUPMORECOMM, see
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 USB Port for Remote Access
 1 Mode
Baud Rate COM2 Mode Settings Quiet Mode Computer Mode
PC match check the PC baud rate and change if needed
 Minimum Requirements
Communications Protocols
Actions
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 RS-232 Communication Parameters for Hessen Protocol
Properly set
Parameter Standard Hessen
 Activating Hessen Protocol
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 BCC
Mode ID Mode Description CMD
To select a Hessen Protocol Type press
To Select a Hessen response mode, press
 GAS TYPE,RANGE,GAS ID,REPORTED
Hessen Protocol GAS List Entry Format and Definitions
 To add or edit an entry to the Hessen Gas List, press
NO, 0, 212, Reported NO2, 0, 213, Reported
Editing or Adding Hessen GAS List Entries
 Deleting Hessen GAS List Entries
To delete an entry from the Hessen Gas list, press
 Setting Hessen Protocol Status Flags
 Unassigned Flags
Default Hessen Status Flag Assignments
Status Flag NAME3 Default BIT Assignment
Operational Flags
 Instrument ID
To assign or reset the status flag bit assignments, press
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 LED State
There is reset
Front Panel LED Status Indicators for DAS
Interface for DAS changes Section
 DAS Channels
DAS Structure
Channels
 CAL Hold OFF
Default DAS Channels
Property Description Default Setting Range Channel
Enabled
 Settings
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 DAS View Touchscreen Functions Button
Viewing DAS Data and Settings
 Editing DAS Data Channels
Translates to the following configuration
NXCNC1 ATIMER, 5
Name NXCNC1 Trigger Event Atimer
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 Manual
 DAS Data Parameter Functions
Changed during data acquisition
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 Stored and reported to the Comm ports
AVG, SDEV, MIN or MAX sample modes see .1.3.3,
Report period
 Report Periods in Progress when Instrument Is Powered Off
 Editing the Number of Records
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 ON/OFF
Holdoff Feature
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 Disabling/Enabling Data Channels
Starting Date Feature
 DAS Configuration VIA Apicom
Remote DAS Configuration
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 Whereas the editing, adding and deleting of DAS channels
DAS Configuration VIA Terminal Emulation Programs
Advised before attempting any DAS changes
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 Remote Control VIA a Terminal Emulation Program
Computer Mode
Interactive Mode
Remote Control VIA Apicom
 Where
Command Syntax
Terminal Mode Software Commands
Command Command Type
 Status Reporting
Data Types
General Message Format
 Model 9110T NOx Analyzer Remote Operation
Remote Access by Modem
AT Y0 D0 H0 I0 S0=0
 To initialize the modem press
Remote Access by Modem
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 Where N is any numeral between 0
Password Security for Serial Remote Communications
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 Calibration Quality Analysis
Model 9110TH NOx Analyzer Calibration Procedures
 Before Calibration
Model 9110T NOx Analyzer Calibration Procedures
Required EQUIPMENT, SUPPLIES, and Expendables
 Example
Calibration Gases
Zero Air
Span Gas
 Measured medium as closely as possible
Data Recording Devices
Span Gas for Multipoint Calibration
2.4. NO2 Permeation Tubes
 ZERO/SPAN Calibration Checks VS. ZERO/SPAN Calibration
4. NO2 Conversion Efficiency CE
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 Outside the allowable range for a reliable calibration
See for troubleshooting tips
Performing a Basic Manual Calibration Check
Performing a Basic Manual Calibration
 Entered properly in the conversion efficiency setting
Setting the Expected Span Gas Concentration
 For troubleshooting tips
 As a calibration source
Manual Calibration with the Internal Span GAS Generator
 CAL on NO2 Feature
Setup for Calibration with the Internal Span GAS Generator
Check is performed
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 Troubleshooting tips
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 Calibration. See for troubleshooting tips
 Setup for Calibration Using Valve Options
 Sample TST TST CAL Cals Setup
Manual Calibration Checks with Valve Options Installed
 Manual Calibration Using Valve Options
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 Autocal Modes
Mode Name Action
Disabled
Automatic ZERO/SPAN CAL/CHECK Autocal
 Analyzer’s sample port
AutoCal Attribute Setup Parameters
For US EPA controlled/related applications
Always be set to OFF
 0030
Sept
100 AM
15.0
 To program the example sequence shown in -4, press
Setup  Acal Programming and Auto CAL Sequence
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 Entr button will disappear from the display
 No Offs No Slope NOX Offs NOX Slope
Calibration Quality Analysis
 GAS Flow Calibration
Separate flow meter is required for this procedure
 Model 9110T NOx Analyzer EPA Protocol Calibration
Calibration General Guidelines
 Spare Parts and Expendable Supplies
Calibration EQUIPMENT, SUPPLIES, and Expendables
 Record Keeping
Calibration Frequency
Calibration GAS and Zero AIR Sources
Data Recording Device
 Definition of Level 1 and Level 2 Zero and Span Checks
Level 1 Calibrations Versus Level 2 Checks
 Equation
GAS Phase Titration GPT
GPT Calibrator Check Procedure
GPT Principle of Operation
 ≤ 2min
 Have to be made, and TR and PR will have to be recalculated
Example GPT Calculation
 Conditions of use against a reliable standard
GPT Multipoint Calibration Procedure
Handbook, Vol. II, Part 1, Appendix
 GPT Calibration System
SET UP for GPT Multipoint Calibration of the 9110T
 Span Calibration
Zero Calibration
 GPT NO2 Check
See the Troubleshooting if there are problems
 Summary of Quality Assurance Checks
Other Quality Assurance Procedures
 Short Calibration Checks
ZERO/SPAN Check Procedures
 Certification of Working Standards
Precision Check Procedure
Precision Check
 Standard
Certification Procedures of Working Standards
References
Other Methods of Establishing Traceability
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 Part Maintenance and Service
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 Model 9110T NOx Analyzer Instrument Maintenance
Maintenance Schedule
 CAL Date Performed Action Freq Check REQ’D
9110T Maintenance Schedule
 Function Expected Actual Interpretation & Action
Predictive Diagnostics
Maintenance Procedures
Predictive Uses for Test Functions
 Replacing the Particulate Filter
Replacing the Sample Particulate Filter
 Turn against the Perma Pure dryer
Risk of causing a significant leak
Changing the O3 Dryer Particulate Filter
Ensure to use proper wrenches
 Changing the Ozone Cleanser Chemical
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 Offsets, which may take 2-3 weeks to disappear
 Replacing the Scrubber
Maintaining the External Sample Pump Pump Pack
Changing the Pump DFU Filter
Rebuilding the Pump
 Procedure for Replacing Filters on Internal Pumps
Procedure for Replacing Filters on External Pumps
 Changing the Internal Span GAS Generator Permeation Tube
Room temperature and will contaminate the entire instrument
Changing the External Zero AIR Scrubber OPT 86C
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 Changing the External Scrubber’s DFU Filter
Zero Air Scrubber Assembly
 HOT Surface Hazard
Changing the NO2 Converter
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 Cleaning the Reaction Cell
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 Replacing Critical Flow Orifices
To clean or replace a critical flow orifice
 From the vacuum port to get the parts out of the manifold
Checking for Light Leaks
 Checking for Pneumatic Leaks
Assembly
Simple Vacuum Leak and Pump Check
 Surfaces
Detailed Pressure Leak Check
 Instrument
Performing a Sample Flow Check
This value is only calculated, not measured
 Model 9110T NOx Analyzer Troubleshooting & Service
General Troubleshooting
 Fault Diagnosis with Warning Messages
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 XXX.X MV
Front Panel Warning Messages
Ozone Flow
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 Can also cause changes in the absolute atmospheric pressure
Fault Diagnosis with Test Functions
OUT of Range reading
Pressure
 Indicated Failures
Diag  Signal I/O Using the Diagnostic Signal I/O Function
 Under this menu
These signals upon exit
 Test Channel Outputs as Diagnostic Tools
Using the Analog Output Test Channel
 12.3.2.1. I2C Bus Watchdog Status LEDs
Using the Internal Electronic Status Leds
CPU Status Indicator
Relay PCA Status Leds
 Relay PCA Status LED Failure Indications
LED Color Function Fault Indicated Failures Status LED ROW
D10 Green NO/NOx Valve D9 Green AutoZero Valve
D1 RED
 About 1 in-Hg per 300 m / 1000 ft
GAS Flow Problems
Zero or LOW Flow Problems
Sample Flow is Zero or Low
 Ozone Flow is Zero or Low
Check pressures
 High Flow
Check if the particle filter is clogged
 Sample Flow is Zero or Low but Analyzer Reports Correct Flow
 Negative Concentrations
Calibration Problems
 Unstable Zero and Span
No Response
 Inability to Zero no Zero Button Calz
Inability to Span no Span Button Cals
 NON-LINEAR Response
 Discrepancy Between no and NOX Slopes
Discrepancy Between Analog Output and Display
 Excessive Noise
Other Performance Problems
Slow Response
 Dirty reaction cell can cause high Auto Zero values
Auto Zero Warnings
 DC Power Supply
AC Main Power
Subsystem Checkout
 DC Power Supply Acceptable Levels
DC Power Test Point and Wiring Color Codes
From
 Touchscreen Interface
LCD/DISPLAY Module
Motherboard
Test Channel / Analog Outputs Voltage
 Step Nominal Output Voltage
12.7.6.2. A/D Functions
Analog Output Test Function Nominal Values Voltage Outputs
Full Scale Output of Voltage Range
 To test the status output electronics
Status Outputs
Ozoneflow
 10 Status Outputs Check
Control Inputs
 Basic PCA Operation Check
Pressure / Flow Sensor Assembly
Sample Pressure Sensor Check
 12.7.7.4. O3 Flow Sensor Check
General RS-232 Troubleshooting
RS-232 Communications
Vacuum Pressure Sensor Check
 RS-232 Programming Notes TAI P/N
Troubleshooting Analyzer/Modem or Terminal Operation
 Doubt, consult the factory
12.7.10.1. NO2  no Converter Electrical System
 Calculating / Checking Converter Efficiency
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 Step
Evaluating NO2  no Converter Performance
 Simplified GPT Calibration
 Concentration must be used must be 440 ppb or more
There must be a minimum of 10% more no than O3 produced
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 NOx Loss
OUT-GASSING no NOX
 Optic Test
Photomultiplier Tube PMT Sensor Module
To activate the optics test, press
 To activate the electrical test, press
 PMT Preamplifier Board
High Voltage Power Supply
 PMT Temperature Control PCA
 12.7.15.1. O3 Generator Override
12.7.15. O3 Generator
 Exit the menu
Internal Span GAS Generator and Valve Options
 Box Temperature Sensor
Temperature Sensor
PMT Temperature Sensor Control
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 Expendables are discussed in Instrument Maintenance
Service Procedures
DISK-ON-MODULE Replacement Procedure
Procedures. Contact Teledyne Customer Service Department
 Sample and Ozone Perma Pure Dryer Replacement
12.8.2. O3 Generator Replacement
Analyzer has warmed up for about 60 minutes
 To calibrate the PMT preamplifier PCA
PMT Sensor Hardware Calibration
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 Between measure and Auto Zero modes
Replacing the PMT, Hvps or TEC
Qualified Personnel
 9110T Sensor Assembly
Ensure to replace the 5 desiccant bags inside the housing
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 10 Relay PCA with AC Relay Retainer In Place
Removing / Replacing the Relay PCA from the Instrument
 Question
Frequently Asked Questions
Answer
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 Analytical Instruments
Technical Assistance
 Chemiluminescence Creation in the 9110T Reaction Cell
Measurement Principle
Model 9110T NOx Analyzer Principles of Operation
 NO2* →NO2 + hν1200nm
Chemiluminescence Detection in the 9110T Reaction Cell
Photo Multiplier Tube PMT
Optical Filter
 Tensit
NOX and NO2 Determination
 XNO2 + yMo→ xNO + MyOz at 315C
 Direct Interference
Measurement Interferences
 Light Leaks
 List of Interferents
Reaction Cell Temperature Control
Gas Interference Type Rejection Method
 Zero a perfect vacuum
Pneumatic Operation
Sample GAS Flow
Both leak tight and not pressurized over ambient pressure
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 Basic Internal Gas Flow for Basic 9110T with Internal Pump
Vacuum Manifold
 Sample Gas Flow Valves and Routing
9110T Valve Cycle Phases
NO/ no
 Critical Flow Orifice
Flow Rate Control Critical Flow Orifices
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 Ozone GAS Generation and AIR Flow
Maintained at a constant temperature
O3 Generator
 10 Ozone Generator Principle
Ozone Generator Dry Air Supply
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 Down, the generator is turned on immediately
Pneumatic Sensors
Ozone Supply Air Filter
Ozone Destruct
 Samplepressure
Sample Pressure Sensor
Vacuum Pressure Sensor
Sample Gas Flow Calculation
 13.2.4.4. O3 Supply Air Flow Sensor
 Electronic Operation
13 9110T Electronic Block Diagram
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 Flash Chip
Disk-On-Module
 Sensor Inputs
 Thermistor Interface
 Reported nor stored
Analog Outputs
External Digital I/O
Motherboard see Section
 13.3.3.7. I2C Data Bus
Only until signal I/O menu is exited
To their normal value/setting
Internal Digital I/O
 Electrical Shock Hazard
15 Relay PCA Layout P/N
 16 Relay PCA P/N 045230100 with AC Relay Retainer in Place
Status LED’s
 Relay PCA Status LED’s
Color Function Status When Lit Status When Unlit
 Valve Control
Watchdog Circuitry
Yellow no 2  no Converter Heater
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 TC1
 TC1
Sensor MODULE, Reaction Cell
TC2
Not Used
 Photo Multiplier Tube PMT
20 9110T Sensor Module Assembly
 PMT preamplifier board provides a variety of functions
PMT Preamplifier
 Principles of Operation
22 PMT Preamp Block Diagram
 23 Typical Thermo-Electric Cooler
PMT Cooling System
 Preamp
Pneumatic Sensor Board
TEC Control Board
PMT
 All AC and DC Voltages are distributed via the relay PCA
Power SUPPLY/CIRCUIT Breaker
 Logic Devices
AC Power Configuration
Sensor Module
Hvps PMT
 Pump Configuration
Configuration Jumpers for Optional AC Heaters
Configuration Jumpers For AC Heaters
 AC Power Configuration for Internal Pumps JP7
 White
AC Configuration Heaters for Option Packages JP6
Power Configuration for Standard AC Heaters JP2
VAC /115 VAC VAC / 240 VAC
 IZS
Power Configuration for Optional Heaters JP6
Jumper Heaters Between Function Color Pins
RED
 Front Panel TOUCHSCREEN/DISPLAY Interface
30 Front Panel and Display Interface Block Diagram
 Lvds Transmitter Board
Software Operation
Front Panel TOUCHSCREEN/DISPLAY Interface PCA
 Adaptive Filter
TEMPERATURE/PRESSURE Compensation TPC
Calibration Slope and Offset
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 Means of Generation
HOW Static Charges are Created
Model 9110T NOx Analyzer Primer on ESD
Static Generation Voltages for Typical Activities
 Damage Susceptibility Voltage
HOW ELECTRO-STATIC Charges Cause Damage
Potentially damaging electro-static discharges can occur
Sensitivity of Electronic Devices to Damage by ESD
 Basic Principles of Static Control
Common Myths about ESD Damage
General Rules
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 Working AT AN ANTI-ESD Work Bench
Working AT the Instrument Rack
 Transferring Components Between Rack and Bench
Opening Shipments from TAI Customer Service
 ESD Hazard
Packing Components for Return to TAI Customer Service
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 Model 9110T NOx Analyzer Glossary
Glossary
Term Description/Definition
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