Displaying PSD Data

 

 

 

 

 

 

If you are performing an internal standard calibration, the

 

 

 

 

 

 

software determines the constants as listed below:

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

PSD Internal

Constant

 

Value Used

 

 

 

 

Standard Calibration

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

One-point

α

 

 

 

Calculated from standard mass

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

β

and γ

 

0

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Two-point or

α

and β

 

Calculated from standard masses

 

 

 

 

three-point

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

γ

 

 

 

0

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

More than three-point

α, β, γ

 

Calculated from standard masses

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Region of The composite spectrum is generated from portions of the

8

segments included

segment traces. The upper mass limit of the composite region

in composite

in each segment is determined by the PSD Mirror Ratio (Rn)

 

 

spectrum

with which the segment was acquired and the mass of the

 

 

precursor ion (mp) (Figure 8-3).

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Seg 1

 

 

 

 

 

 

 

 

 

 

included in composite

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

included in composite

 

 

 

 

 

 

 

 

Seg 2

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Seg 3

 

 

 

included in composite

 

 

 

R1 x mp

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

(If first segment acquired

 

 

 

 

 

 

 

 

 

 

 

 

 

 

R2 x mp with PSD Mirror Ratio=1.0,

 

 

 

Seg 4

 

 

 

 

 

 

 

 

 

 

upper limit is

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

slightly higher than

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

precursor ion mass)

 

 

 

 

 

 

 

 

 

 

 

 

R3 x mp

 

 

Figure 8-3 Portions of Segment Traces Included in the Composite Spectrum

 

Data ExplorerSoftware User’s Guide

8-7