Peak Detection and Labeling Troubleshooting

Table 9-12 Charge State and Isotope Determination Troubleshooting—Mariner

Only (Continued)

Symptom

Possible Cause

 

Action

 

 

 

 

 

 

 

Spectrum peaks labeled

Charge state

Adjust parameters. See:

 

 

with incorrect charge state

determination parameters

“Peak Processing

 

 

when charge state labels

are set such that peaks

 

 

 

parameters

 

 

are selected

are determined to have no

 

 

 

 

(spectrum data only)”

 

 

 

charge

 

 

 

(continued)

 

on page 3-26

 

 

 

 

 

 

 

 

Section 3.2.5,

 

 

 

 

 

Charge State

 

 

 

 

 

Determination and

 

 

 

 

 

Examples

 

 

 

 

 

 

 

 

Noise between isotope

Increase %Base Peak

 

 

 

peaks is detected

Intensity or %Max Peak

 

 

 

 

Area to eliminate noise.

 

 

 

 

See “Basic Settings

 

 

 

 

(spectrum data only)” on

 

 

 

 

page 3-22.

 

 

 

 

 

 

 

 

 

Apply noise filter. See

 

 

 

 

Section 5.7, Noise

 

 

 

 

Filtering/Smoothing.

 

 

 

 

 

 

9

Monoisotopic peak not

Peak detection charge

Adjust parameters to

 

labeled correctly

state parameters are not

correctly identify the

 

 

set correctly, the software

monoisotopic peak. See

 

 

 

is identifying the tallest

“Peak Processing

 

 

 

peak in a cluster as the

parameters (spectrum

 

 

 

monoisotopic peak

data only)” on page 3-26.

 

 

 

 

 

 

 

 

 

 

Data ExplorerSoftware User’s Guide

9-21